Product ID:SYNTHOL SYNTHETIC ENAMEL, 8010 HARDENER
MSDS Date:04/01/1991
FSC:8030
NIIN:00N022638
MSDS Number: BYHGK

MARTIN-SENOUR CO

101 PROSPECT AVE NW
CLEVELAND, OH 44115
US

Emergency Phone: 216-566-2917

Info Phone: 216-566-2902

Cage: 16772

MARTIN-SENOUR CO THE DIV SHERWIN-WILLIAMS CO

CHICAGO, IL 60608-5724 US

Cage: 16772

RESP FOR WHOLE TIME OF SPRAYING & UNTIL ALL VAPS

RTECS: 9999999ZZ

AREA WHERE THIS PROD IS BEING USED UNLESS EQUIPPED

RTECS: 9999999ZZ

ARE ACGIH TLV 10 MG/M3 (TDUST), OSHA PEL 15 MG/M3

RTECS: 9999999ZZ

ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE) (CERCLA) VP

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 4%

OSHA PEL 150 PPM

ACGIH TLV: 150 PPM; 200 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ISOPHORONE DIISOCYANATE POLYMER

CAS: 53880-05-0

Fraction By Weight: 30%

OSHA PEL N/K

ACGIH TLV: N/K

ISOCYANIC ACID, METHYLENE (3,5,5-TRIMETHYL-3,

CAS: 4098-71-9

RTECS: NQ9370000

Fraction By Weight: 0.3%

OSHA PEL N/K

ACGIH TLV: 0.005 PPM

VOLATILE ORGANIC COMPOUND & VOC LESS WATER AND EXEMPT

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

ASSOC RPTD & PRLNG OVEREXP TO SOLVS W/PERM

RTECS: 9999999ZZ

DELIBERATELY CONCENTRATING & INHALING THE CONTENTS

RTECS: 9999999ZZ

LOOSELY. WASH SPILL AREA WITH SOAP AND WATER.

RTECS: 9999999ZZ

HEATERS. TURN OFF STOVES, ELEC TOOLS &

RTECS: 9999999ZZ

CODE. USE APPRVD BONDING & GROUNDING PROCS. KEEP

RTECS: 9999999ZZ

CNTNRS W/COMPLETE & APPROP LABELING. DO NOT TAKE

RTECS: 9999999ZZ

CHRONIC (LONG-TERM) LUNG/BRTHG PROBS OR IF

RTECS: 9999999ZZ

W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST. AVOID

RTECS: 9999999ZZ

COATING MAY CNTN MATLS CLASSIFIED AS NUISANCE

RTECS: 9999999ZZ

DURING SANDING/ABRADING OF DRIED FILM. IF NO

RTECS: 9999999ZZ

SOLVENT NAPHTHA (PETROLEUM), LIGHT AROMATIC; (LIGHT

CAS: 64742-95-6

RTECS: WF3400000

Fraction By Weight: 9%

OSHA PEL N/K

ACGIH TLV: N/K

7.1

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 3%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM; 125 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

5.9

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 54%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM; 150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ALCOHOLS & ACETATES CAN BE ABSORBED
THRU SKIN. ACUTE: IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERVOUS
SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON & POSS DEATH. HDCH,
DIZZ, NAUS & LOSS OF COORDINA TION ARE INDICATIONS OF EXCESSIVE
EXPOSTO VAPS OR SPRAY MISTS. REDNESS & ITCHING OR BURNING SENSATION
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: MAY INDICATE EYE/EXCESSIVE SKIN
EXPOS. CHRONIC: PRLNGD OVEREXP TO LISTED SOLVS MAY CAUSE ADVERSE
EFTS TO LIVER, URINARY, BLOOD FORMING, CARDIOVASCULAR & REPRO
SYSTEMS. PERSONS SENSITIVE TO I SOCYANATES WILL EXPERIENCE INCRD
ALLERGIC RXN ON RPTD EXPOS TO ISOCYANATES IN ENAMEL HARDENERS.
REPORTS HAVE (ING 8)
Medical Cond Aggravated by Exposure:ENAMEL HARDENERS MAY CAUSE ALLERGIC
RESPIRATORY &/OR SKIN REACTION IN SUSCEPTIBLE PERSONS OR
SENSITIZATION. THIS EFFECT MAY BE DELAYED SEVERAL HOURS AFTER
EXPOSURE.

First Aid:INHAL: IF ANY BREATHING PROBLEMS OCCUR DURING USE, LEAVE AREA
& GET FRESH AIR. IF PROBLEMS REMAIN OR OCCUR LATER, IMMEDIATELY GET
MEDICAL ATTENTION. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP &
WAT ER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. EYES:
FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTENTION. INGEST: GET MEDICAL ATTENTION.

Flash Point:80.0F,26.7C
Lower Limits:0.5%
Upper Limits:6.7%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZS ARE PREF.
WATER MAY BE USED TO COOL CLSD (SUPDAT)
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPK & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN
EXPOS TO EXTREME HEAT. APPLICATION TO HOT SURFS (SUDPAT)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT. VENT & REMOVE
W/INERT ABSORB. IF ENAMEL HARDENERS ARE SPILLED, ALL PERS IN AREA
SHOULD BE PROTECTED. COVER SPILL W/ABSORB MATL. DEACTIVATE SPILLED
MATL W/10% AMMONIUM HYDR OXIDE SOLN (HOUSEHOLD AMMONIA). COVER (ING
10)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPK & OPEN FLAME.
DURING USE & UNTIL ALL VAPS ARE GONE: KEEP AREA VENT. DO NOT SMOKE.
EXTING ALL FLAMES, PILOT LIGHTS & (ING 11)
Other Precautions:THESE PRODS MAY BE MIXED W/OTHER COMPONENTS BEFORE
USE. BEFORE OPENING PACKAGES, READ & FOLLOW WARNING LABELS ON ALL
COMPONENTS. NO PERSON SHOULD USE ENAMEL HARDENERS OR BE IN AREA
WHERE HARDENERS ARE BEING USED IF THEY HAVE (ING 14)

Respiratory Protection:WHERE OVERSPRAY IS PRESENT, NIOSH/MSHA APPRVD
POS PRESS AIR SUPPLIED RESP (T1C19C) SHOULD BE WORN. IF UNAVAIL,
PROPERLY FITTED, NIOSH/MSHA APPRVD ORG VAP PARTICULATE RESP MAY BE
EFTIVE. FOLLOW RESP MF R'S DIRECTIONS FOR USE. WEAR (ING 19)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS IS MAINTAINED
BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS 1910.94,107,108.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EMER EYE BATH & DELUGE SHOWER
. USE BARRIER CREAM ON EXPOSED SKIN WHEN USING ENAMEL HARDENERS.
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
FIRE FIGHT PROC: CNTNRS TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLOS
WHEN EXPOS TO EXTREME HEAT. EXPLO HAZS: REQS SPECIAL PRECS. DURING
EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY
NOT BE IMMED APPARENT. OBTAIN MED ATTN. MATL TO AVOID: PRESS IN &
POSSIBLE BURSTING OF CLOSED CNTNRS.

Boiling Pt:B.P. Text:>132F,>56C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:0.933
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:76-100

Stability Indicator/Materials to Avoid:YES
CONTAM OF HARDENERS W/WATER, ALCOHOLS, AMINES & OTHER CMPDS WHICH REACT
W/ISOCYANATES, MAY RSLT IN DANGEROUS (SUPDAT)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.

Waste Disposal Methods:WASTE FROM PROD MAY BE HAZ AS DEFINED UNDER RCRA
40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE
APPLIC EPA HAZ WASTE NUMBERS. INCIN IN APPRVD FACILITY. DO NOT
INCIN CLSD CNTNR. DISP OF I/A/W FED, STATE & LOC REGS REGARDING
POLLUTION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.